|
Steam Purity Limits
for Steam Turbines - Key Parameters |
|
Location |
Parameter µg/kg |
Expected range |
Limit Value |
Action within 1 week |
Action within 24 h |
Action within 1 h |
|
Live Steam |
c.con (µS/cm(250C)) |
0.06 - 0.2 |
0.2a.b |
0.2 - 0.5c |
0.5 - 1.0 |
>1.0 |
| |
Sodium |
0-5d |
5d |
5-10 |
- |
- |
| |
Silica |
3 - 5 |
20 |
- |
- |
- |
| |
Irone |
2 - 5 |
20 |
- |
- |
- |
| |
Copper f |
0 - 1 |
3 |
- |
- |
- |
|
Attemperator Spray |
c.con (µS/cm(250C)) |
as
live steam |
| |
Sodium |
| |
Silica |
| |
Irone |
| |
Copper f |
- For conventional
phosphate dosing, a limit value of 0.3 µ S/cm (250C) may be
applied, provided it can be shown that the dominant contribution
to the additional conductivity is due to the phosphate ion.
- higher value may
be acceptable when an organic oxygen scavenger or volatile pH
conditioner is used, provided that it is shown. For example, by
analysis of chloride and sulphate that the increase is not due
to aggressive contaminants.
- If chloride
exceeds 20 µg/kg, action within 24 h is necessary.
- Values depend on
boiler dosing , 5µg/kg is normally attainable as a limit value
under AVT. In some plant, up to 10 µg/kg may be appropriate
under sodium compound dosing.
- Iron may not need
to be monitored in plant where there is no history of excessive
iron transport
problems.
- Only monitored in
plant with copper alloy heat exchanger tubing, particularly
high-pressure boiler
systems.
- Only used in
conjunction with monitoring of saturated steam to indicate live
steam purity.
|
| Abbreviated Terms :
|
|
For the purpose of this
technical specification, the following abbreviated terms are used
: |
|
AVT |
all volatile treatment |
|
BWR |
boiling water reactor |
|
c.con |
cation conductivity |
|
CT |
caustic treatment |
|
EPT |
Equilibrium phosphate
treatment |
|
FAC |
flow accelerated
corrosion |
|
IWC |
International Water
Conference |
|
OT |
oxygenated treatment |
|
PT |
Phosphate treatment |
|
PWR |
pressurized water
reactor |
|
Reference : TS 61370 © IEC : 2002 Steam Purity Limits for Steam
Turbines - Key Parameters |
| |
|
|
|
|
Steam Turbines - Steam
Purity |
|
High c.con |
Chloride sulphate |
Condenser leak |
Check condenser |
|
Demineralization plant
failure |
Check demineralization
plant |
|
Organic impurities from
raw water |
Check demineralization
plant |
|
Increased organic
additive decomposition |
Check dosing rates |
|
Condensate polisher
slippage |
Check condensate
polisher operation |
|
cation exchange resin
fines |
Check condensate
polishers |
|
Carbon dioxide due to
air inleakage at condenser |
Check condenser for
leaks |
|
High sodium |
|
Condenser leak |
Check condenser |
|
Increased boiler water
dosing |
Check dosing rates |
|
Increased boiler water
carryover |
Check condition of
boiler for foaming, high level or moisture separator defect |
|
Demineralization plant
failure |
Check demineralization
plant |
|
High Silica |
|
Increased boiler water
carryover |
Check condition of
boiler as above |
|
Demineralization plant
failure |
Check demineralization
plant |
|
Increase in raw water
non-reactive silica content |
Check raw water quality |
|
Mixed bed condensate
polisher slippage |
Check condensate
polisher operation |
|
High iron |
|
High levels in feedwater
and increased corrosion product transport by carryover or impure
attemperator spray |
Check conditioning
especially for low pH |
|
Use of materials prone
to iron oxide release |
Check material
performance |
|
High Copper |
|
High levels in feedwater
and increased corrosion product transport by carryover or impure
attemperator spray. |
Check feedwater purity
for high oxygen or high pH |
|
Reference : TS 61370 © IEC : 25002 Steam turbines - steam purity
actions on deviations from guidelines |